Analysis Of Zimbardos The Perils Of Obedience - 1189 Words

Stanley Milgram, an American social psychologist, writes in his article â€Å"The Perils of Obedience† about an experiment he designed which forced participants to either obey the demands of an authority figure, in this case the experimenter, or to turn against obedience and refuse to proceed in the experiment (Milgram 78). He found from this experiment that a minority of the participants refused to obey orders by the experimenter; therefore, most of the participants followed the orders given by the experimenter knowing it would result in the learner’s pain (Milgram 80). Milgram believes his results did not prove that these participants were sadists or mass murderers; however, his results did prove that ordinary people simply obeying orders can†¦show more content†¦Traci Stein Ph.D., an integrationist at Psychology Today, writes in her article â€Å"Dealing with Everyday Sadists and Other ‘Dark Personalities’† that everyday sadists will neve r take responsibility for harming another person, and they may seek harm in others because they believe it will benefit them in some way (Stein). In this case it is perceived that Stein and Milgram would agree that those capable of sadistic, inhumane acts will react in those manners without taking responsibility like the teachers in the Milgram experiment. On the contrary, Zimbardo effectively writes in his article about how dehumanization is portrayed within the six -day experiment by both the guards and the prisoners because of the way they were treated by each other (Zimbardo 111). If true, then this is also true in everyday life when people are treated differently than they are used to and will react abnormally or inhuman for that moment. Dr. Metin BaÅŸoÄŸlu, Head of Section of Trauma Studies at Kings College London and the Istanbul Centre for Behavior Research and Therapy, writes in the article â€Å"Cruel and Inhuman Treatment Causes More Mental Damage Than Physical Tortu re† about his findings of people being held captive in hostile, humiliation, psychological manipulation situations which appear to cause more mental than physical damage to the peopleShow MoreRelatedComparative Analysis a Few Good Men Essay1591 Words   |  7 PagesComparative Analysis: A Few Good Men â€Å"You dont need a patch on your arm to have honor.† Lt. Daniel Kaffee, portrayed by Tom Cruise, says at the end of the movie to Lance Cpl. Dawson after the final ruling is read, stating PFC. Downy and Lance Cpl. Dawson are innocent but are dishonorably discharged from the military. A Few Good Men portrays the negative impact on military personally from strict obedience. Lt. Daniel Kaffee, along with Lt. Cdr. JoAnne Galloway and Lt. Sam Weinberg; played byRead MoreStephen P. Robbins Timothy A. Judge (2011) Organizational Behaviour 15th Edition New Jersey: Prentice Hall393164 Words   |  1573 Pagesof systematic study. Identify the major behavioral science disciplines that contribute to OB. Demonstrate why few absolutes apply to OB. Identify the challenges and opportunities managers have in applying OB concepts. Compare the three levels of analysis in this book’s OB model. MyManagementLab Access a host of interactive learning aids to help strengthen your understanding of the chapter concepts at www.mymanagementlab.com cott Nicholson sits alone in his parents’ house in suburban Boston

In This Study, We Will Learn How A Psychopath Female, Amy

In this study, we will learn how a psychopath female, Amy Dunne, is diagnosed with a personality disorder, as well as a differential diagnosis. We will learn how some of her actions in the movie will example of how a person with a personality disorder will or could act. The characters that will be discussed in this paper are the main character Amy Dunne, her husband Nick Dunne, also her ex-boyfriend Desi. Amy primary diagnosis is Antisocial Personality Disorder and her differential diagnosis is Borderline Personality Disorder. There was an alternative diagnosis, which was Narcissistic Personality Disorder, but it was thrown out, because Amy only meets one of the criteria. A brief description of the movie is Amy finds out that her husband†¦show more content†¦Amy created â€Å"Amazing Amy† which is a series of children’s books about this little perfect girl that overcome all these obstacles life throw at her. She had to live up to expectations that she couldnâ⠂¬â„¢t, in some of her books she mentions her failure. In the movie she mentions she tried out for a sports team and didn’t make it, while Amazing Amy made the varsity team. Furthermore Amazing Amy had a dog as a child, in reality Amy Dunne didn’t have one. The movie doesn’t really discuss the etiology after the Amazing Amy scene. Amy is manipulative, deceitfulness, violates the law, irritability and aggressiveness, lack of remorse, impulsivity plan ahead, reckless disregard for safety of self or others. Amy fits the Antisocial Personality Disorder criteria and show symptoms of Borderline Personality Disorder criteria. Antisocial Personality Disorder is a pervasive pattern of disregard for and violation of the rights of others(p.400). Borderline Disorder is a pervasive pattern of unstable interpersonal relationships, self-image, affect, and impulsivity(p.400). The criteria for Borderline Personality Disorder that Amy meets following: a pattern of unstable and intense interpersonal relationships, there is some emptiness, and she may also have anger. Her relationship with her parents is intense,Show MoreRelatedRastafarian79520 Words   |  319 PagesRastafari This page intentionally left blank Rastafari From Outcasts to Culture Bearers Ennis Barrington Edmonds 2003 198 Madison Avenue, New York, New York 10016 Oxford University Press is a department of the University of Oxford It furthers the Universitys objective of excellence in research, scholarship, and education by publishing worldwide in Oxford New York Auckland Bangkok Buenos Aires Cape Town Chennai Dar es Salaam Delhi Hong Kong Istanbul Karachi Kolkata Kuala

Gawadar Port and Sino-Pak Relations Free Essays

string(230) " prepared for the Pentagon entitled Energy futures in Asia Which states that Beijing has already has set up electronic eavesdropping posts at Gwadar which monitor ship traffic through the Strait of Hormuz and the 30 Arabian Sea \." Topic: – Gwadar Port and Sino-Pak relations. Table of Contents:- a . Introduction b . We will write a custom essay sample on Gawadar Port and Sino-Pak Relations or any similar topic only for you Order Now Background c . Historical Location Chapter #1 a. Pakistan China relations b. Strategic Cooperation c. Economic Forecast Chapter # 2 a. Geographical Importance b. Advantages of Gwadar Port Chapter #3 a. China’s Involvement in Gwadar project b. China’s Gain Chapter #4 a. Gwadar port as development Project b. Construction c. Port Operation Conclusion [1] Introduction :- Gwadar port is located at Gwadar city at the entrance of the Persian Gulf on Arabian Sea and about 460 km west of Karachi from Balochistan , Pakistan . Gwadar port , is a deep –sea warm water port ,being constructed in two phases with heavy investment from china . Gwadar has had huge geostrategic significance on my accounts. In 1993 ,Pakistan started technical and financial feasibilities for the development of Gwadar port . The Gwadar port project started on 22 March 2002a. The first phase has been completed but officials expect the port’s initial three berths to be operational in the later months of 2007 . Gawadar port was inaugurated on March 19,2007 . Gawadar port is Pakistan’s first deep port that has the capacity to serve virtually all sorts of cargo ships of any size. Background :- Gwadar is located on the southwestern coast of Pakistan,close to on the persain Gulf. More than 13 million of oil pass through the strait . It is strategically located between three increasingly important regions : the oil –rich Middle East, heavily populated south Asia and the economically emerging and resource –loaded region of central Asia . The Gwadar port is expected to generate billions of dollars in revenues and create at least 2 million jobs. In 2007 the government of Pakistan handed over port operations to PSA Singapore for 25 years,and gave it the status of a Tax Free Port for the following 40 years . Historical Location :- The Makran region surrounding Gwadar by ancient Bronze age people which settled in the few oases . It later became the Gedrosia region of the Achaemenid Persian empire . It later became the Gedrosia region empire . It is believed to have been conquered by the founder of the Persian empire ,Cyrus the Great. During the home ward march of Alexander the great ,his admiral ,Nearchus,led a fleet along the modern –day Makran coast and recorded that the area was dry , mountainous, and inhabited by the Ichthyophagoi an Greek rendering of the Persian â€Å"Mahi Khoran ’’( which has itself become the modern word â€Å" Makran† ). After the collapse of Alexander’s empire the area was ruled by Seleucus Nicator ,one Of Alexander’s generals . The region then came under â€Å" local rule † around about 303 BC and the region remained on the sidelines of history for a millennium ,until the Arab – Muslim army of Muhammad bin Qasim captured the town of Gwadar in AD 711 and over the intervening amount of time the area was countested by various powers , including the Mughals the safavids. Portugese explorers captured and sacked gwadar in the late 16th century and this was then followed by almost two centuries of local rule by the various Balochi tribes . In 1783 , the Khan of Kalat granted suzerainty over Gwadar to Taimur Sultan , the defeated ruler of Muscat . This governor was then ordered to control the nearby coastal town of chah Bahar ,where the Gwadar fort was built during Omani rule. In 1958 , the Gwadar farm was transferred to Pakistan . It was then made part of the Balochistan province in 2002 , the Gwadar project was begun in the town . The government of Pakistan intends to develop the entire area in order to reduce its reliance in shipping on the port of Karachi . In addition to expanding port facilities , the projects aims to build industrial complexes in the area and to connect the town via a modern highway to the rest of Pakistan . By the end of 2004 the first phase had been completed . [2] Chapter # 1 Pakistan – China Relations on Gwadar Port :- Gwadar Port Karakoram Highway scheduled to be inaugurated on 30th June 2006, . fter the Chinese agreed to provide $ 198 million of the $248 million required for phase 1 of the 26th project. Here is important to note that in the beginning china was not ready to hold this project but finally agreed to fund it provided that it had â€Å" Sovereign guarantees to the port facilities† . Just 250 miles from the state of Hormuz ,through which nearly 40 % of the world’s oil supplies flow, the port is strategically located to serve as a key shipping point in the region . It is of the great strategic value as it augments Pakistan’s imports in the region ,while allowing china to expand and secure its crude oil import routes and simultaneously gain approach to the Persian Gulf . According to MOU signed between China and Pakistan ,China is also to built a 90 km link connecting the Chinese side of Karakoram highway to the Russian built highway network that connects all the five Central Asian Republics . This regional highway network will directly Gwadar to Xinjiang and the landlocked Central Asian 28 Republics . The Karakoram highway and the coastal highway will both serve as vital trade routes and considering that the existing Karakoram highway already connects Western China to Pakistan ,any further expansion of the line along with prospective linkages to Gwadar road would make it the shortest and most viable route connecting Gwadar 29 to western china . This shows china’s attempt to exert its influence far beyond its borders to sustain its security interest ,as well as merge its friendship with Pakistan through large scale joint projects. Through the construction of the Gwadar port ,Beijing also will gain considerable influence in the region . giving it a strategic entrance to the Arabian Sea and the Indian Ocean, while allowing it to closely monitor US naval activity and US – Indian maritime cooperation . The doubtlessly is a cause for alarm and unease to both India and US as the port will enable China to monitor its energy shipments from the Persian Gulf. American suspicion of Chinese intentions at Gwadar is corroborated by an internal report prepared for the Pentagon entitled Energy futures in Asia Which states that Beijing has already has set up electronic eavesdropping posts at Gwadar which monitor ship traffic through the Strait of Hormuz and the 30 Arabian Sea . You read "Gawadar Port and Sino-Pak Relations" in category "Essay examples" In addition , the port and the other supporting infrastructure will help mix Pakistan in to the Chinese economy by out sourcing low tech ,basic production and manufacturing jobs , making it into a giant factory floor for China . Having invested $400 million in the project , the port will be available for Chinese imports and export through overland links that stretch across the Karakoram 31 Highway . For Pakistan as well ,the benefits are profound ,where to quote President Musharraf , â€Å" as and when needed the Chinese navy could be in Gwadar to 32 give befitting replies to every one . This statement was further reinforced by Pakistan’s recent designation of the port area as â€Å" a sensitive defense area† . Gwadar would inhibit India’s ability to blockade Pakistan , and permit China to supply Pakistan by land and sea during wartime . Essentially , Pakistan is interested in the project to gain strategic leverage so that it is less vulnerable to the dominant I ndian navy . The construction of the port and the highway, by making Pakistan a regional trade –hub for commercial traffic ,will also boost domestic economic development ,and influence the geo – strategic environment of the region . The port will enable the transfer of Central Asia’s vast energy resources to world markets , earning Pakistan significant profits in transits fees, as well as attract considerable investment into Balochistan . In addition , discussions are already underway to designate the Gwadar port as a free trade ,while some members of the Pakistani business community advocate the eventual designation of the Gwadar port as an export processing zone with special incentives extended to Chinese companies . Moreover ,the opening of international trade through Gwadar can create new stakeholders in Afghanistan who will become beneficiaries of the transportation trade to Central Asia . Gwadar thus presents a good opportunity for fostering good neighborly relations between Pakistan and the region to its immediate northwest . However, the success of the port and ,in general ,the effectiveness of the agreements signed between the two nations will depend essentially on internal development in Pakistan. [3] Strategic co-operation:- Gwadar is the height of Sino-Pakistani strategic cooperation . It is a modern port city that is supposed to link Central Asia, western china, and Pakistan with markets in Mildest and Africa . It’s supposed to have roads stretching all the way to China. Some reports in the American media , however , have accused Pakistan and China of building a naval base in the guise of a commercial seaport directly overlooking international oil shipping lanes . The Indians and some other regional actors are also not comfortable with this project because they see it as commercial competition. What Mr. Bugti’s regional and international supporters never expected is Pakistan moving firmly and strongly to nip his rebellion in the bud. Even Mr . Bugti himself probably never expected the Pakistani state to react in the way it did to his betrayal of the homeland . He was killed in a military operation where scores of his armed force surrendered to Pakistan army soldiers . US intelligence and their Indian advisors could not cultivate an immediate replacement for Mr Bugti . So they moved to plan B. They supported Abdullah Mehsud, a Pakistani Taliban fighter held for five years in Guantanamo Bay, and then handed over back to the Afghan government, only to return to his homeland, Pakistan, to kidnap two Chinese engineers working in Balochistan, one of whom was killed during rescue operations by the Pakistani government . Islamabad could not tolerate this vague figure , who was creating a following among ordinary Pakistanis camouflaged as a Taliban while in reality towing a vague agenda . He was rightly eliminated earlier this year by Pakistani security forces while secretly returning from Afghanistan after meeting his handlers there. 4] Economic Forecast :- The government declared port a â€Å" Special zone† in the budget ,2003-2004 . All banks will open their branches ,five star hotels will be built ,offshore banking will be started ,factories, warehouses, and storage will be set up ,the tourism industry will be promoted in the area ,an export processing zone will be set up , making Pakistan a very attractive place for direct foreign investment ,and Gwadar port a regional hub of trade and investment activities. Chapter# 2 Geopolitical Importance: The Gwadar port is emerging as a place of great strategic value. It is enhancing Pakistan’s importance in the whole region. It is extending from the Persian Gulf through the Indian Ocean to South Asia and the Far East. Gwadar is located on the Southwestern coast of Pakistan. It is very close to the important Straits of Hormuz, through which more than 13 million bbl of oil passes. It is strategically located between three increasingly important regions of the world: heavily populated South Asia, the oil rich Middle East and the economically emerging and resource rich Central Asia. The construction of The Gwadar deep sea port is just one part f a larger development plan which includes building a network of roads connecting Gwadar with the rest of Pakistan, such as the 650 km Coastal Highway to Karachi and The Gwadar-Turbat road(188 km). This network of roads connects Pakistan with China through the Indus Highway. China, Kazakhstan, Kyrgyzstan, Pakistan and Uzbekistan are developing extensive rail and road links from Central Asia and the Chine se province of Xinjiang to the Arabian Sea Coast. The Pakistani Government has initiated several projects with china’s technical and financial assistance. These projects are inaugurated to develop Gwadar’s strategic location as a good transit and trade point. The primary project is the construction of deep sea port at Gwadar, which would enable high –volume cargo movement to and from the landlocked Central Asian States. The new port will also include conversion facilities to allow for the movement of natural gas as a part of plans for the termination point for the Turkmenistan-Afghanistan-Pakistan natural gas pipeline. The secondary project is coastal highway which is connecting Gwadar to Karachi. Its cost, $200 million will be completely financed by Chinese. Gwadar will serve as a port of entry for gas and oil to be transported by land to Western regions of China. The significance of Gwadar port is great to both, Pakistan and China. In near future Pakistan will be able to make strong strategic plans because in past Indian navy made it very difficult for Pakistan navy base at southwest Karachi. China is going to be recipient of Gwadar’s most accessible international trade routes to the Central Asian republics and Xiajiang. Beijing can receive cargo to and from Gwadar through shortest route, Karachi to Peshawar, by extending its East West Railway from the Chinese border city of Kashi to Peshawar in Pakistan’s North West. To supply oil from the Persian Gulf to Xiajiang, the rail network could also be. Internal rail network of Pakistan can also provide china with rail access to Iran. Rail access will however be hampered somewhat by difference in gauge: Pakistan-1676; Central Asia-1524mm; China and Iran-1435mm. Advantages of Gwadar Port: Gwadar is located on the Gulf of Oman which is close to the entrance of Persian Gulf. It is about 460 km west of Karachi. Pakistan started feasibility studies for the development of a major deepwater sea port at Gwadar in 1993. The port project began on 22 March 2002. Its first phase completed in December 2005. The construction of the port has prompted other major infrastructure projects in area. This includes the 700 km Makran Coastal highway which is now complete. The road links Karachi with several ports along the coast including Pasni, Ormara and Gwadar. It will be extended to Iranian border in future. The Highway has reduced travel time to Karachi from 48 hrs to only 7 hrs. Other road projects include the Gwadar-Quette-Chaman road which is completed now, and a road link to the town of Khuzdar in Eastern Balochistan. There are plans for a terminal for passenger ships. The Civil Aviation Authority of Pakistan has embarked 3000 acres of land for Gwadar International Airport . It will be built 26 km away to the northeast of existing airport towards Pasni. Its cost approximation is between $200-250 million. The new airport would be given International status. It will operate under open sky policy. There are also plans to improve facilities at the existing airport. Railways: In 2005, Minister of Railway said,† The government is focusing on laying the Havelin-Kashghar (China) and Quetta-Kandahar (Afghanistan) railway tracks†. In 2006. Minister of railway announced that Gwadar will be connected to Pakistan Railway network at an expected cost of $1. 25 billion (Rs. 75 billion)[5] Chapter# 3 China’s Involvement in the Gwadar port: Chinese Premier Wen Jiabao inaugurated the Gwadar deep sea port. Through which china would be able to take a Giant Leap Forward in gaining a foothold in the Persian Gulf region. It will advance what a recent Pentagon report describes as Beijing’s â€Å"String of Pearls† strategy that aims to protect China’s energy security at home and project Chinese power overseas. Gwadar is a fishing village on the Arabian Sea Coast in Pakistani province of Balochistan. Balochistan shares border with Iran and Afghanistan to the west. Gwadar is just 72km from Iranian border. The important thing is Gwadar’s closeness to the Persian Gulf. It is situated near the entrance of this strategic body of water, and about 400 km from the Strait of Hormaz, a major channel for global oil supplies. Pakistan identified Gwadar as a port site in 1964. But significant steps toward making the proposal a reality were taken in 2001, when China agreed to participate I n the construction and development of Gwadar deep sea port. The arrival of United States in Afghanistan in 2001, at China’s doorstep encouraged Beijing to step up its involvement in the Gwadar project. Chinese vice premier Wu Bangguo laid the foundation for Gwadar port in March 2002. China’s involvement in the project is immense. The total cost of the project is estimated US$1. 16 billion, of which China has contributed about $198 million for the first phase, almost four times the amount Pakistan has invested for this phase, which include of three multi-purpose ship berths. China has invested $200 million for building a highway, which connects Gwadar port with Pakistan’s largest city, Karachi (an other sea port on the Arabian Sea). The second phase which may include nine more berths, an approach channel and storage terminal, will also be financed by China. Beside its financial help China has sent 450 engineers and provided technical expertise for the project. In recent year, bilateral trade has steadily increased between China and Pakistan. Both countries have highlighted the immense economic returns that development of Gwadar port holds out for them, as well as others in the region. China’s Gains:- Zia Haider, an analyst at the Washington-based Stimson Center, writes that Gwadar provides China â€Å"a transit terminal for crude-oil imports from Iran and Africa to China’s Xinjiang region†. The network of road and rail connecting Pakistan with Afghanistan and Central Asian republics that is envisaged as part of the Gwadar project and to which China will have access would provide Beijing an opening into Central Asian markets and energy sources, in the process stimulating the economic development of China’s backward Xinjiang region†. [6] For China, Gwadar’s strategic value is because of its closeness to the Strait of Hormuz. About 60% of China’s energy supplies come from the Middle East. China has been anxious that the US, due to its high presence in region, could stop these supplies. â€Å"Having no blue water navy to speak of, China feels defenseless in the Persian Gulf against any hostile action to choke off its energy supplies,† points out Tarique Niazi, a specialist in resource based conflicts, in the Jamestown Foundation’s China Brief. [7] A presence in Gwadar provides China with a â€Å"listening post† where it can monitor US naval activity in the Persian Gulf, Indian activity in the Arabian Sea. A recent report titled â€Å"Energy Futures in Asia† produced by defense contractor Booz Allen Hamilton for the Pentagon notes that China has already setup electronic eavesdropping posts at Gwadar, which are monitoring maritime traffic through the Strait of Hormuz and the Arabian Sea. Drawing attention to China’s â€Å"string of pearls† strategy, the reports point out that â€Å"China is building strategic relationships along the sea lanes from the Middle East to South China Sea in ways that suggest defensive and offensive positioning to protect China’s energy interests, but also to serve broad security objectives†. 8] The port and naval base in Gwadar is part of â€Å"string of pearls†. The other â€Å"pearls† in the string include facilities in Bangladesh, Myanmar, Thailand, Cambodia and South China Sea that Beijing has acquired access to by diligently building ties with governments in these countries. The Pentagon report sees Chinaà ¢â‚¬â„¢s efforts to defend its interests along oil shipping sea lanes as â€Å"creating a climate of uncertainty† and threatening â€Å"the safety of all ships on the high seas†. This perception neglects the fact that China’s â€Å"string of pearls† strategy has been prompted by its sense of insecurity. The United States irresistible presence in the Gulf and the control of its exercises over the Malacca Strait, through which 80% of China’s oil imports pass, has added enormously to Beijing’s fears that Washington could stop its oil supply, in the event of hostilities over Taiwan. China’s foothold in the Arabian Sea has set off alarm bells in India, Iran and US. For India, China-Pakistan collaboration at Gwadar and China’s presence in the Arabian sea intensifies its feeling of hold by China from all sides. Iran sees the development of Gwadar port in its neighborhood as likely to grind down the significance of its ports, especially Chabahar port that India has helped to construct-to central Asia and Afghanistan. However, Iran’s good relations with Central Asian Republics and Afghanistan would help it to maintain its advantage Pakistan’s Gwadar port. Ultimately, the extents to which Pakistan and China are able to reap economic and strategic gains from Gwadar project depend on the challenges to it from within their borders. Chapter# 4 Development Projects: Oman: Oman has offered $100 million aid for the development of social and infrastructure facilities in Balochistan. Out of $100 million, Oman has provided $7 million for extending of runway at Gwadar Airport, construction of jetties, up gradation of Gwadar Hospital and construction of power house. Oman is also financing construction of Gwadar Hoshab Road, water supply scheme in Gwadar area and construction of irrigation dams. Pakistan and Oman have signed a number of agreements which include Avoidance of Double Taxation, Promotion and Protection of Investment, Cultural, Educational and Technical Co-operation, Agreement on cooperation between Oman Chamber of Commerce and Industry and FPCCI, Maritime Boundary Agreement and Agreement to establish Pak-Oman Joint Investment Company. The closeness to Oman is an advantage to Pakistan. Around 70,000 Pakistani citizens are participating in the development of Oman. Omani assistance for construction of Gwadar port is going a long way in promoting economic relations between Gwadar-Pakistan and Central Asian States. 9] Pakistan: Pakistan is linking Gwadar with Karachi through networking of roads. It’s also enabling Central Asian States in north, to use Gwadar as a port for their trade. Water supply is being improved, seven jetties are being constructed and local fishermen are being given motor engine run boats. The local hospital is also upgraded. A number of e lectric power generation projects are also being carried out in Gwadar and its surroundings. The Quetta Electric Supply Company (QESCO), a subsidiary of Wapda, has geared up the work for the building the power transmission line. It is expected to be completed soon. Airport: Gwadar has a small airport which is basically meant for Fokker aircraft. But the need is to expand this airport and enlarge its runway to facilitate the landing of wide body aero-planes. CAA has upgraded the Gwadar Airport for the landing of Airbuses. Gwadar airport is open air and after its inauguration the jet planes are also landing at it. A sum of 2. 3 million dollars is being utilized from Omani grant. The Pakistan government and the Civil Aviation Authority are also contributing Rs563. 35 million for this purpose. Dry Port: China wants to set up a dry port near the Pakistan-China border, so that Western China could also benefit from Gwadar seaport. It will create the ribbons of economic activity and hundreds of new jobs along proposed highway linking Gwadar with the Karakoram highway in the north. Construction: Dubai ports World, announced on June 1, 2006 that it will spend $10 billion to develop transport infrastructure and real estate in Pakistan. Dubai port World is also discussing the possibility of the company taking over operational management of Gwadar port in Balochistan. Emaar Prosperities, announced on May 31, 2006 there real estate developments in the cities of Islamabad and Karachi in Pakistan. The projects, with a total investment of $2. 4 billions, will include a series of master planned communities that will set new benchmarks in commercial, residential and retail property within Pakistan. In addition the conglomerate signed a exceptional $43 billion deal to develop two island resorts, Bundal Island and Buddo Island, over the next decade. Port Operations: Port of Singapore took over the management of Gwadar port by the end of January 2007. Port of Singapore was the highest bidder for the Gwadar port after Dubai Ports world backed out of the bidding process. Originally, the chairman of DP world, Sultan Ahmad bin Sulayem, who met President Pervez Musharraf on May 5th 2006, expressed a strong hope for the management of facilities at the strategic Gwadar deep-sea port and development of infrastructure in the southern port city everywhere in Pakistan. But a decision was taken not to bid, when India’s Security Council voiced concerns bout DP World’s projects in India, alongside its plan in Pakistan, and Sultan Ahmad bin Sulayem assured the Indians their pull out was well considered and Indian need not have any security concerns. The port will now be in competition with Dubai. Conclusion: The project of Gwadar port which was commenced on 22 March 2002, by China will enhance co-operation between Pakistan and China in the field o f engeering and technology. The significance of this project is great for both countries. Gwadar is located on the Gulf of Oman close to the entrance of Persian Gulf. China is going to be the beneficiary of Gwadar’s most accessible international trade routes to Central Asian Republics and Xinjiang. Pakistan’s rail network can also provide China with rail access to Iran. For Pakistan, the economic returns from Gwadar port stem from its location near the Strait of Hormuz, through which 40% of the world oil passes. Gwadar could emerge as a key shipping point, bringing Pakistan desirable income, and when combined with the surrounding areas could become a trade hub, once rail and road links connect it to the rest of Pakistan, Afghanistan and Central Asia. A road from Gwadar to Saindak is the shortest route between Central Asia and sea. Gwadar would provide landlocked Afghanistan and the Central Asian republics with access to sea. Goods, oil and gas reserves from these countries could be shipped to global markets through Gwadar port. The development of Gwadar could bring economic gains to backward Balochistan. The infrastructure development of the province could make it an attractive investment destination. Bibliography: 1) Stefan Helders, World Gazetteer. â€Å"Gwadar†. 2) Daily Times. Gwadar deep seaport to generate two million jobs†. 3) Khaleeq Kiani, â€Å"Dawn. 40-year tax relief for Gwadar port operators†. 4) Jona Lendering, Livius. org. â€Å"Gedrosia†.. 5) Dott. Beatrice Nicolini, Oman Studies Centre. â€Å"International trade networks: The Omani Encalve of Gwadar† 6) Gwadar vision , http://www. gwadar. com. pk/new/gwadar. asp? var=vision 7) Development projects http://www. gwadar. com/new/gwad ar. asp? var=devppojectsver the next decade 8) Latif, S. M. 1892. Lahore. Lahore: New Imperial Press, reprinted 1981, Lahore: Sanndhu Printers. ) Low, D. A. The Political Inheritance of Pakistan. London: Macmillan. 1991. 10) Papanek, G. F. Pakistan’s Development: Social Goals and Private incentives. Cambridge, Massachusetts: Harvard University Press. 1967. 11) Ziring, Lawrence. Pakistan: The Enigma of Political Development. Boulder, Colorado: Folkestone. 1980. 12) Pakistan among Top 10 Reformers (September12, 2005). Retrieved on 2006-03. 13) World Bank Country Classification Groups,(July 2006 data) Pakistan economy profile 2007. 14) http://www. cia. ov/library/publications/the-factbook/rankorder/2003rank. html 15) http://www. cia. gov/libraray/publications/the-worfactbook/rankorder/2087rank. html 16) http://www. cia. gov/libraray/publications/the-worfactbook/rankorder/2078rank. html 17) Business, Stakeholders and Strategic Responses in Pakistan Article written by Imran Ali of Lahore University of Management Sciences. 18) Gwadar: China’s Naval outpost on the Indian ocean Tarique Niazi, The Jamestown Foundation, China Brief 2/28/2005 19) Decoding India –Pakistan-China relations by Rajinder Puri Sep 13,2006. 0) Concluding Remarks at the Pakistan Development Forum 2006 by John Wall, World Bank Country Director for Pakistan (html). World Bank. 21) http://www. forbes. com/lists/2005/03/30/05f2000land. html. 22) http://www. asianresearch. org/articles/2528. html. 23) http://www. nationmaster. com/encyclopedia/Gwadar-port 24) http://www. travel-culture. com/pakistan/gawadar. shtml 25) http://livenreal. com/news/index. php/history-of-gwadar/ ———————– 26) [1] http://www. nationmaster. com/encyclopedia/Gwadar-port 7) [2] http://livenreal. com/news/index. php/history-of-gwadar/ [3] Gwadar vision , http://www. gwadar. com. pk/new/gwadar. asp? var=vision [4] Development projects http://www. gwadar. com/new/gwadar. asp? var=devppojectsver the next decade [5] www. wilkipedia. com/pakistan/gwadar-port/html [6] www. atimes. com/atimes/south_asia/gc04df06. html [7] http://www. asianresearch. org/articles/2528. html [8] www. atimes. com/atimes/south_asia/gc04df06. html [9]http://www. travel-culture. com/pakistan/gawadar. shtml How to cite Gawadar Port and Sino-Pak Relations, Essay examples

Censorship of the grapes of wr Essay Example For Students

Censorship of the grapes of wr Essay The Grapes of Wrath by John Steinbeck is considered a classic novel by many in the literary field. The trials and tribulations of the Joad family and other migrants is told throughout this novel. In order to gain a perspective into the lives of Oakies, Steinbeck uses themes and language of the troubling times of the Great Depression. Some of these aspects are critiqued because of their vulgarity and adult nature. In some places, The Grapes of Wrath has been edited or banned. These challenges undermine Steinbecks attempts to add reality to the novel and are unjustified. In 1939, The Grapes of Wrath was published and came under fire for its content. Vulgarity and the misrepresentation of a preacher were the main complaints that led to the ban and burning of the novel from St. Louis, Missouri libraries in September 1939. Vulgarity may be prevalent in the book, but it has its purpose. Steinbeck used some vulgar terms to accurately represent the lingo and slang that was used by the people of the 1930s. Most of the terms that were considered vulgar may be a bit distasteful, but is nothing that is not heard on the streets today. Extreme profanity is not extraneous in the novel, in fact, it is tame compared to slang terms used today. Casy, the former preacher that was traveling with the Joads, is not be given the connotation as the most holy man. Casy did not consider himself a minister at the time The Grapes of Wrath takes place. But I aint a preacher no more is spoken many times by Casy in denial that he is a man of the cloth. Indeed, Casy is brutally ki lled in the novel, but it does not go into graphic, violent detail. Once again, Casys feelings against the employers and government were common to the time and were used to state that idea. Another point of controversy lies on The Grapes of Wraths closing sequence. In this finale, an old man nurses from Rose of Sharon, a young women whose baby was delivered stillborn. Some believe this is pornographic, sexually oriented, and improper, especially for young children. In fact in some states, the sequence is taken out. This sequence may be a vulgar, but it is an essential element to the novel and is in no way pornographic. It shows the desperation of the migrants to do anything to survive, no matter what the implications may entail. Those who are missing this ending, such as those who read editions in Texas, are missing this important element of The Grapes of Wrath. These readers may never fully understand the lives of migrants in the 1930s . The novel may have some adult content, but it was never meant to be read by young children. The target audience, ages over 14, can look beyond the visual picture and fully ascertain the sections deeper meaning. Others may critique Steinbecks use of socialistic and anti-government messages. During the 1930s, these ideas were very common. In fact, Upton Sinclair, a socialist writer, was nearly elected governor of California. Living conditions, the opposition between the Californians and the Oakies, and the inability to break out of the depression all added to beliefs of the times. Steinbeck was not advocating socialism, he was just reflecting the times. Without these individual beliefs of the reds and other people that showed either socialistic or anti-establishment messages, the reader would get a dry, unfulfilled perspective of the lives of people during the Great Depression. Censorship does have its place in society. There are many things that are too risqu, degrading, and should not be shown. Pornography, extreme sexual content, and extreme gratuitous violence does not have its place in literature or in society. The Grapes of Wrath does not have any of these above aspects. Of those who choose to ban this book and other works of literature with questionable themes, many of them are wrapped up in political correctness. In literature, life should be shown like they it is, not as someone would like it to be. As much as political correctness advocates would like to change things for the better, they cannot change the past no matter how hard they try.

What is the role of War poetry Show how it has performed this role throughout history Essay Example

What is the role of War poetry Show how it has performed this role throughout history Essay Meticulous accounts of tragic occasions defined in the timeline of history, war poetry dates back hundreds of years, dignifying and glorifying the bravery of such young soldiers that died and survived, fighting for their country and their beliefs.Anglo-Saxon war poetry tended to be written directly at or after the scene of the battle, meaning the accounts could be accurate and have significant information included in them. For example, in The Battle of Maldon, the poet could record exactly what was said by Byrhtnoth and the leader of the Vikings, and write their speeches to every last word. In addition, the poet includes tiny little fragments of feature, for example Then Byrhtnoth spoke, board-shield raised, shook slender spear, gave speech This is evidence of how detailed the poem can become, by expressing little actions and positions the leaders and armies perform.Another large stylistic point of Anglo-Saxon poetry is their use of alliteration. The Battle of Maldons line structure is almost entirely based on alliterative words, containing at least two per sentence. For instance, Brave seamen sent me to you, told me to say you should send quickly silver for safety and itd be sensible for you and roused, resolute, made his reply. The effect of this is to create a sense of rhythm and impact for the reader, making the poem memorable for them and to strengthen the argument and opinion of the poem.In The Battle of Maldon, the Anglo-Saxon army is eager to fight and decline gold put forth by the Vikings. This shows that the Anglo-Saxons persuade people to fight for the good of their country instead of compromising, and they are proving that if you are a soldier then you will have eternal magnificence and immortality through poems, even if you do not win the war. For example, It would be humiliating for you to be off with our shillings to your ships without a fight, now so far youve made an entry into our country! The poet uses repetition of our in this sentence, emph asising, again, to defend your land and your will as a team.Shakespeares techniques were rather different compared to those of the Anglo-Saxons. He did not write at the sight of the war, but sometimes hundreds of years later. For instance, Henry V was written about one hundred years after the battle actually occurred; meaning Shakespeare could use his imagination more freely and decide how the story went for himself. However, this could also result in the poem not being completely exact and significant pieces of detail being left out, leaving it up to Shakespeare to create his own twists in the story. The result is a more imaginative account.Another interesting difference between Henry V and The Battle of Maldon is that Shakespeares Henry V was not written as propaganda, it was written for theatre. This is what Shakespeare mostly intended to write for. Therefore, rather than resembling poetry, his work was designed to be acted as a stage play and contained mainly long speeches and s oliloquies, for example the St Crispins Day speech in Henry V.A huge distinction between the Charge of the Light Brigade and the Battle of Maldon is the rhyme. For instance, Stormd at with shot and shell, While horse and hero fell, They that had fought so well Alliteration is used in the Battle of Maldon to give the poem a sense of rhythmic impact, whereas in the Charge of the Light Brigade, Tennyson used rhyme as an alternative. Consequently, the reader can read with more ease and direction, and there is a jollier, more regular rhythmic pattern to the poem.Another technique of The Charge of the Light Brigade is its repetition. For example, Flashd all their sabres bare, Flashdas they turnd in air. The outcome of this poetic method is to emphasise light flashing on a sword, which is a visual image.Disabled is a very contemporary poem in terms of vocabulary, grammar, image and style. It was written just after World War 1 by Wilfred Owen, probably the best known First World War poet. T his poem is very different compared to the others. It uses lots of enjambment, the structure and meaning of the lines of poetry being carried directly over to the next line without a break. For example, Only a solemn man who brought him fruits Thanked him; and then inquired about his soul. This is used effectively to create a feel of naturalistic motion in the poem.Furthermore, Owens use of depressing and vivid language and imagery give Disabled a much more disheartening tone than the other poems. For instance, He sat in a wheeled chair, waiting for dark, And shivered in his ghastly suit of grey. The effect of the saddening vocabulary, such as dark, shivered, ghastly and grey, and style in and of the poem help create a sympathetic approach towards the soldier whos lost all his limbs. Its putting you in the position of the young man, which helps you to realise his pain.Some war poems encourage participation in war, some discourage it. There have been some vast changes in war poetry t hroughout the centuries for many different reasons, and many poets have been recognised for those changes. However, you still have to notice some of the big and little similarities between them, and acknowledge that through all that has happened in history, knowledge has been passed on from generation to generation through an incredible and demanding art.

Censorship in Fahrenheit 451 essays

Censorship in Fahrenheit 451 essays Many things come to mind when the word censorship is involved. The Merriam Webster Dictionary states that censorship is stopping the transmission or publication of matter considered objectionable. In Ray Bradburys novel Fahrenheit 451, censorship plays an enormous role and is noted to be the most important theme. Themes are the fundamental and often universal ideas explored in a literary work. Censorship in Fahrenheit 451 has a major effect on the societys knowledge and characteristics in the novel. In the futuristic world Bradbury has created in the science fiction novel Fahrenheit 451, firemen start fires rather than extinguishing them. People of this society do not think independently nor do they have meaningful conversations. They dont even have an interest in reading books. Rather than that, they watch an extreme amount of television on wall-size sets and listen to Sea-shell radio which is attached to their ears. People drive extremely fast due to lack of appreciation for nature. It was a pleasure to burn. So goes the opening sentence of the Bradburys story. It grabs the readers attention and immediately tells where the unfortunate hero, Guy Montag, stands on the idea of book burning. Being the protagonist of Fahrenheit 451 Montag is by no means a perfect hero. Montags faith in his profession and his society begins to decline almost immediately after the novels opening passage. Montag comes across a gentle seventeen-year-old girl named Clarisse McClellan, who opens his eyes to the dark emptiness of his life with her innocent questions and unusual love for people and nature. Being faced with the complication of books for the first time, Montag is often frustrated, confused, and overwhelmed. He is often rash, unclear, self-obsessed, and too easily influenced. At times he is not even aware of why he does things, feeling that his hands...

Reflective Report Essay Example | Topics and Well Written Essays - 1000 words - 1

Reflective Report - Essay Example The research that I have done deconstructed my view and my perception of what is Nike. The horrendous experience of the workers of Nike is no small thing. People do work and take jobs so that they can have a better life. It is not something that one will do and yet at the end of the day one turns out to be more miserable; more miserable because one has experienced becoming less of a human and be treated as machine whose sole purpose is to produce. One can argue, as Bhagwati (2007) claims that Nike workers are better off, but that is not true. Hand to mouth survival is not human survival. It is the way animals in the jungle live. Unfortunately, this reality is experienced by the workers of Nike because the salary that Nike gives is not enough to feed and provide semblance of a good life to its workers, while Tiger Woods has been given millions of dollars. The injustice that Nike perpetuates in its factories bears witness to the deplorable condition of third world workers, who bounded by poverty and structural corruption in their own countries, have no better alternative in improving their lives. It is like the choice is between two evils – you suffer in the quagmire of poverty or work in Nike and hopefully one can have something to eat (even just a little). Workers’ stories show the other side of Nike, its dark side. I cannot help but be emphatic with the unethical working condition in Nike. As a student of management, the stories of the workers of Nike has shown me that management can really do something in making the lives of the workers better. The management is in the position to carry out company policies that will make the working conditions and the workers’ status improved, healthier and humane. This is our function and our vision as managers – as we try to gain profit for the company that we are servicing, we should never forget that there are also stakeholders of the company whose interest should also be upheld. The companyâ €™s stakeholders are as important as its shareholders. Their interest should be protected and addressed as the way to the present and future of management and of the organisation is finding the balance between shareholders’ interest and stakeholders’ interests. I believe that this is difficult but I also think that is the way management ought to be – responsive to both the shareholders and stakeholders concerns. I believe gone are the days when firms exist for profit and profit alone. It is not the way how the market responds now. The market is the people who see the importance and value of human rights, labour rights and corporate social responsibility. In fact, they are willing to pay more for products that hold up causes that they support and, at the same time, they are willing to withdraw support to products and corporations who have been unethical and abusive of their workers, of the environment and of their stakeholders. This is what happened to Nike. Some of their regular buyers refuse to buy their products anymore. I am one of them. Moreover, the research has opened to me the reality of the challenge that management faces in the current period. I think the unethical behaviour of Nike toward its workers is the standard of what should not be done. What has happened to the workers of Nike is not the norm in management and workers relation but it is that which should be avoided. Others may find me idealistic but the reality of the

Adam Smith's Theory Research Paper Example | Topics and Well Written Essays - 750 words

Adam Smith's Theory - Research Paper Example Born in 1723 and died in 1790, Smith left a legacy in his model Wealth of Nations that has been an influential contribution in economics. In brief, the theory identifies the basic principles that nation acquire wealth and function effectively when individuals use capital and proficiency at their own diplomacy. His model revealed the nature of country’s prosperity as many learn the principles of economics. Up-to-date, his arguments are used and cited in debates as many learn from his great insights. Nevertheless, some people disagree with his assumption as many view him as an activist of callous individualism. Regardless of the way he is viewed, his theory is paramount in the economics field. How the economy does stem from his theory and importantly economists assume that the theory is accurate in how the world’s economy operates. At this point, this paper seeks to analyze the theory and lay a discussion of its pros and cons. Wealth of Nations In his theory wealth of nat ion, Smith noted that wages and prices might reach optimal level when freedom of using capital and skills as per wish is imposed (Smith, In Cannan & Lerner, 1937). He taught by examples of new products, which he argued that, when invented prices are usually high until when others discover the profit potential, and join the field then prices go down. Indeed this can be outlined in today’s electronics where such scenarios take place. ... According to O'Rourke and Smith (2007), the theory explored that there cannot be consumption if there is no production. To explain further, Smith’s theory affirmed cars do not just exist there is a process through which they are put together in production to manufacture cars. Similarly, capitalism works in this way in the sense that when a car is manufactured, those in need of a car search for it in the car factory and purchase as per their choice of the car. In the 21st Century, people do not just walk in the car factory and request to purchase the car but they are purchased by a dealership and later sold to clients. The main point that Smith wanted to highlight is that, one can break capitalism in two parts consumption and production. In this case, there cannot be consumption without production and vice versa. Applicability This law is applicable in today’s society in that one cannot purchase products at the market without being manufactured and supplied by a differen t party. Still, one cannot eat without preparing or acquiring food and cannot be in a house that has not been constructed. From his theory, Smith assumed that the market force ensured there is right invention of goods and services. The theorist based his idea on the aspect of free market economy whereby consumers have the free will to choose what they need. Smith perceived capitalism as the main aspect, which drives, and motivate the economy. He believed that it motivates companies and individuals to gain and accumulate profits. To support his argument, Smith developed two theories through a research on production in Europe during industrial revolution. The two theories are moral sentiments and wealth of nations, which

The novel the help by kathryn stockett Essay Example | Topics and Well Written Essays - 1000 words

The novel the help by kathryn stockett - Essay Example The diverse views of the characters indicate the behaviour of the characters, which help us understand the character development in this novel. For the case of Skeeter, we see her change her priorities throughout the novel. For instance, at first, she aspires to become a journalist for a well-known paper; she began writing answers for a local magazine and later she is seen offering advice on cleaning and cooking among other house chores. The author makes Skeeter to appear different from other white women by exhibiting her bravely, which is admirable by the audience (Kathryn, 69). She comes out strong as a defender of the house help. She exposes all the bad life the maids undergo under the hands of her friends. This is true when we see her long-term relationship with Stuart ends. The character development of Skeeter can be well approached through a focus of her relationship with situations and other characters such as Constantine and her author Kathryn Stockett. One of the fundamental moves that shape Skeeter’s character development as the protagonist in the novel The Help is her decision to move away from the social helm held by the white women. This allowed her to shape her character as exemplary amongst the white dominated populace that lived discriminative of the black house cleaners. It is observable that her decision is not expectable in the setting of this novel. This implies that, she takes a bold step conscious of the outcome which includes discrimination by her friends, which is evident. It is satisfactory that, the Skeeter character revolves around her relationship with other characters and certain scenarios in the novel. In the thirteen chapters of the novel, Skeeter is seen as a character that seeks the truth, kind and committed to help the less advantaged in the society. Constantine is a black woman hired to take care of Skeeter. Skeeter turns to develop very strong and close relationship with the woman.

Mechanisms of Adsorption of Aormatic Nitrogen Compounds

Mechanisms of Adsorption of Aormatic Nitrogen Compounds MECHANISMS OF ADSORPTION OF AORMATIC NITROGEN COMPOUNDS AND AROMATIC COMPOUNDS ON METAL-ORGANIC FRAMEWORKS (MOFs) by JUN DAI Metal-Organic Frameworks (MOFs) constitute a class of novel porous materials which have attracted significant interest due to their application in separation, storage, catalyst and sensing. Large surface area and porous cavity make MOFs excellent absorbents with huge uptake capacity. In this paper, we studied adsorption mechanisms of adsorption of indole and naphthalene on Basolite F300, Basolite A100 and MIL-100 (Fe) by two complementary spectroscopic methods. Fluorescence spectroscopy and near-UV/Visible diffuse reflectance spectroscopy study demonstrate that naphthalene is quantum confined within the mesoporous cavity in F300. On the other hand, indole is weakly electronically bound to Fe (III) CUS in F300 and forms adsorption complex with F300. Direct spectroscopic proof of adsorption complex is provided by near-UV/Visible spectroscopy and fluorescence spectroscopy. Quenching of ligand-based fluorescence of A100 by indole is suggested and we propose adsorption of indole and napht halene onto A100 via Ï€-Ï€ interaction, spectroscopic proof is provided by fluorescence spectroscopy.   Table of Contents Title Abstract Acknowledgements and Dedication Table of Contents 1 Introduction 1.1 Metal Organic Frameworks (MOFs) 1.2 Clean Fossil Fuels 1.3 Nitrogen Aromatic Compounds in Fossil fuels 1.4 Aromatic Compounds in Fossil Fuels 1.5 Methods of Denitrogenation 1.5.1 Microbial Denitrogenation 1.5.2 Hydrodenigrogenation (HDN) 1.5.3 Adsorptive Denitrogenation (ADN) 1.6 Activation of Open Metal Sites of Metal-Organic Frameworks 1.7 Adsorption of Aromatic Compounds and Aromatic N-heterocyclic Compounds on mesoporous MOFs with CUS: MIL-100 (Fe) and F300 1.8 Adsorption of Aromatic Compounds and Aromatic N-heterocyclic compounds on microporous MOFs without CUS: MIL-53 and A100 1.9 Research Objective 2 Experimental 2.1 Metal Organic Frameworks 2.2 Solvents, Aromatic compounds and N-containing compounds 2.3 Activation and Hydration of Metal-organic frameworks 2.4 Fluorescence Spectroscopy 2.5 Near UV-Vis Diffuse Reflectance Spectroscopy (near UV-Vis DRS) 2.6 Model Fuels 2.7 Solid Mixture of Aromatic and Aromatic N-hetrocyclic compounds with MOFs 2.8 Stoichiometric adsorption complex of F300 and naphthalene in eicosane matrix 2.9 Kinetic adsorption of liquid indole on Basolite F300 (FeBTC) in liquid phase 2.10 Stoichiometric adsorption complexes of indole/naphthalene with MOFs 2.11 UV radiation 3 Results 3.1 Spectroscopic Studies of adsorption of naphthalene and indole on mesoporous F300 and MIL-100 (Fe) with CUS 3.1.1 Solid Mixtures of MOFs and organic aromatic compounds 3.1.2 Fluorescence spectrum of pure naphthalene List of Figures Figure 1: Structure of MIL-100 (Fe) (see as S1 in supplementary) Figure 2: Structure of MIL-53 (Al) (see as S2 in supplementary) Figure 3: Common nitrogen compounds existing in fossil fuels Figure 4: Pathways for the transformation of quinoline Figure 5: Fluorescence spectrum of (A) 0.08 M liquid solution of naphthalene (NAP) in n-heptane, ÃŽ »exc = 280 nm, bandwidth: Exc. Slit 5 nm/Emi. Slit 5nm. (B) 0.08 M liquid solution of NAP in n-heptane with multi-Gaussian curve fitting Figure 6: Fluorescence spectrum of (A) pure naphthalene (NAP) ÃŽ »exc = 280 nm, bandwidth: Exc. Slit 5 nm/Emi. Slit 5nm (B) pure NAP with multi-Gaussian curve fitting List of Tables Table 1: MOFs used in this research and structure information Table 2: Physical property of common nitrogen aromatic compounds existing in fossil fuels 1 Introduction 1.1 Metal Organic Frameworks (MOFs) Porous materials are well studied and widely used in science and engineering industry. Recently, a novel kind of porous material ‘Metal-Organic Frameworks (MOFs)’ has emerged as potential competitor. MOFs are crystalline hybrid inorganic-organic porous solid formed by chemical metal-linker bounding1. Metal-Organic Frameworks (MOFs) constitute a class of novel porous materials which have attracted significant interest due to their application in separation, storage, catalyst and sensing. The use of MOF as stationary phase in high resolution GC separation of aromatic hydrocarbons has also gained significant attention2. In comparison with adsorption on the MOFs in gas phase which has been well studied and understood, adsorption on the MOFs in liquid phase is much less known. MOFs have extremely large surface area and porous cavity, which make them excellent adsorbents with huge uptake capacity. As a class of coordination compound repeated by metal or metal clusters as SBUs (second building units) and organic linkers, the cavity ranged between that of Zeolite and mesoporous silica3. Regarding the structures, variety of MOFs can display either 2 dimensional or 3 dimensional structures depend on different organic linkers. It is also indicated by J. R. Karra and K. S. Walton that the relation between pore size and guest molecule size plays an essential role in the adsorption4. The MOFs being investigated in this research are mesoporous and microporous MOFs. For mesoporous MOFs the pore size can vary from 2 nm to 50 nm, while for microporous MOFs the pore size is less than 2nm. Pore size can be a key in adsorption on MOFs due to micropore filling mechanism2, which suggests adsorption capacity depends on molecular cross-sectional area rather than minimum diameter. MOFs are structurally stable under ambient environment. It is reported by many authors that MOFs remain stable under increased temperature and under oxygen. In this research, our investigation mos tly focuses on several common MOFS, and their commercial names are Basolite C300, Basolite F300, Basolite A100 and MIL-100 (Fe) (MIL=Materials of Institute Lavoisier). All Basolite C300, Basolite F300 and Basolite A100 are bought commercially, and MIL-100 (Fe) is made with the collaboration of Dr. Jing Li from Rutgers – New Brunswick. Table 1 shows the basic physical information of the MOFs used in this research. Table 1: MOFs used in this research and structure information MOFs/formula Surface area/m2g-1 Pore dimension/Ã… Pore dimension Ref. BET Basolite F300 1300~1600 21.7 3D Sigma-Aldrich,5 Basolite A100 1100~1500 7.37.7 1D Sigma-Aldrich, MIL-100 (Fe) 2200 25, 29 3D 5 MIL-100 family MIL-100(M) (M=Cr, Fe, Al) refers to a family of mesoporous Metal-Organic Frameworks built up from metal clusters and benzene-1, 3, 5-tricarboxylic (BTC) linkers. These MOFs possess large surface area and have recently attracted tremendous attention for applications in adsorption and separation due to the coordinated unsaturated sites (CUS) which can provide chance for Lewis acid-base interaction between guest molecules and metal ions or metal clusters. In Metal-organic frameworks, metal sites (SBUs) are coordinated with organic linkers. Open metal sites (CUS) may be available on these SBUs. CUS are very important in gas storage, separation, sensing, catalysts, and even biological systems6. Considerable amount of research on the adsorption of small molecules have been done recently. Evidence has shown open metal sites have essential influence on adsorption property in MOFs. It is reported that open Cu2+ metal sites in HKUST-1 contribute significantly to the high acetylene storage capa city7. Moreover, MOFs with CUS such as HKUST-1 are used in chromatography separation due to its specific feature to distinguish strongly and weakly electron donating analytes8. In additional, MIL-100 (Fe3+, Cr3+, Al3+) has been shown to have strong preference to adsorb N-heterocyclic compounds (Lewis base) in mixtures910. Hence, open metal sites can be potential Lewis acid sites, the possible interactions between guest molecules and open metal sites will be examined and discussed in this paper. In our research, MIL-100 (Fe) will be used to investigate the adsorption mechanisms between guest molecules such as indole or naphthalene and sorbent MOFs. Besides MIL-100, there is a commercially made MOF named Basolite F300, which has a similar chemical composition. Both Basolite F300 and MIL-100 (Fe) are built up by Iron and BTC linkers. However, due to the poor crystallinity, the actual structure of F300 is still not known at this time. Difference in iron content and carbon content in F300 and MIL-100 (Fe) is shown by D. Amarajothi and his co-workers5. The iron mass content in F300 and MIL-100 (Fe) are respectively 25% and 21%. The carbon mass content in F300 and MIL-100 (Fe) are respectively 32% and 29%. Pore dimension in F300 and MIL-100 (Fe) are respectively 21.7 Ã… and 25/29 Ã…. Structure of MIL-100 (Fe) is shown below: Figure 1: Structure of MIL-100 (Fe) (see as S1 in supplementary) MIL-53 family There are many types of MOFs that undergo hydrolysis, while there are other MOFs that remain stable within water. Water stable MOFs start to showing potential applications in drug delivery and imaging11. Many MOFs containing Al as metal sites and amino acids as organic linkers are stable in aqueous solution, and it is also possible to synthesize them in aqueous environment12. MIL-53(M) (M= metal as Al13, Cr14, Fe15, In16, Sc17) is a common family of microporous MOFs and has excellent water stability. Figure 2: Structure of MIL-53 (Al) (see as S2 in supplementary) The one dimensional pore structure of MIL-53(Al) is built by chains of corner-sharing octahedra aluminum clusters AlO4(OH)2 and anion form of benzene-1,4-dicarboxylic acid (BDC) as organic linkers connecting infinite numbers of metal clusters. MIL-53 (Al) has rhombic channels which have dimension of 7.3 x 7.7 Ã…. A huge Langmuir surface area of 1600 m2/g makes MIL-53 (Al) an efficient adsorbent. MIL-53 (Al) has extraordinary thermal stability up to 773 K. It is believed that the structure of MIL-53 (Al) undergoes a reversible structural change during process of adsorbing/desorbing water molecules, and is described as ‘breathing’13. The so-called ‘breathing’ process interchanges between large-pore (lp) form (Al(OH)[O2C-C6H4-CO2]) and narrow-pore (np) form (Al(OH)[O2C-C6H4-CO2]H2O) 13. The lp form has a dimension of 8.5 x 8.5 Ã… and is obtained when activated upon high temperature and under high vacuum, which takes away excess free BDC acids, oxygen and water trapped in the cavity during synthesis. The lp form is capable of adsorbing water molecules in vapor at room temperature, as a result, the MIL-53 (Al) shifts to its’ np form. As shown in the formula, the np form contains one trapped water molecule every unit or cavity. Hydrogen bonds are found to form between carboxylic groups on the linkers and adsorbed water molecules. Due to this ‘breathing’ feature, applications on selective adsorption of various compounds in gas phase have already gained interest and being reported14. The np form of hydrated MIL-53 (Cr) is able to selectively adsorb CO2 in presence of CH4 in gas phase. Upon adsorption of CO2 but not CH4, MIL-53 (Cr) returns to its lp form with an increased cavity volume of 1522.5 Ã…3 from np volume of 1012.8 Ã…3. In our research, we used Basolite A100 MOF from the BASF, which is commercially available and is equivalent to MIL-53 (Al). Similarly, A100 is build up with AlO4(OH)2 octahedral clusters connecting by BDC linkers, and gives a surface area of 1084 m2/g and pore volume of 0.51 cm3/g as determined by N2 physical-adsorption at 77 K. Additionally, XRD pattern of A100 is proved to resemble that of MIL-53 (Al)18. G. Blanco-Brieva and his co-workers have studied adsorptive removal of aromatic sulfur compounds from model liquid fuels on thermally activated A10019. 1.2 Clean Fossil Fuels Combustion of sulfur and nitrogen containing compounds in fossil fuels will bring adverse effect to public health, environment and economy. It is widely recognized that nitrogen compounds are normally carcinogenic and mutagenic. Separation of heterocyclic compounds from petro-chemical feedstock has become an urgent application leading to clean liquid fossil fuels. Fossil fuel is a primary source of energy on the earth, the intensive use of fossil fuels has raised environmental concerns. Beginning in 2006, the Environmental Protection Agency (EPA) began an ambitious program aiming to reduce the sulfur content of diesel fuels. As of July 11, 2010, the EPA required that the concentration of sulfur content in diesel fuels not exceed 15 ppm20. For certain ultra-clean gasoline, diesel fuels and jet fuels, sulfur level needs to be lower than 1 ppm21. Hydrodesulfurization (HDS) of diesel fuel has become an essential research interest, while the presence of nitrogen compounds in middle-distil late oil inhibits the ultra-deep hydrodesulfurization22232425. In HDS, sulfur compounds are hydrogenated to hydrocarbons and H2S over catalyst such as Zeolites9. However, the nitrogen aromatic compounds in crude oil are found to compete for the active sites on these catalysts to inhibit a deep HDS26,27. This gives rise to the necessity for denitrogenation in fossil fuels. Moreover, the combustion of nitrogen compounds in petroleum leads to the formation of NOx oxides, which is a group of highly reactive and persistent species and contributes directly to acid rain and greenhouse effect. The life time of NOx oxides in atmosphere is 120 years before being removed or destroyed through chemical reactions. The impact of 1 pound of NO ­x on warming the atmosphere is over 300 times that of 1 pound of carbon dioxide. EPA first set standards for NO2 in 1971, setting both a primary standard (to protect health) and a secondary standard (to protect the public welfare) at 0.053 parts per million (53 ppb), averaged annually28. Also the presence of nitrogen aromatic compounds in fossil fuels can lead to poisoning of refining catalyst, which will eventually cause a decrease in yield. Thus, denitrogenation is necessary for deep desulfurization and has drawn significant interest around the world due to the increasingly rigid regulations and fuel specifications in many countries. 1.3 Nitrogen Aromatic Compounds in Fossil fuels Fossil fuels are naturally-formed fuel that contains significant level of heterocyclic aromatic contaminants. There are some representative sulfur aromatic compounds such as benzothiophene (BT) and dibenzothiophene (DBT), representative nitrogen aromatic compounds such as indole and quinoline. Nitrogen aromatic compounds content in crude oil averages around 0.3%. Although the concentration of nitrogen compounds in crude oil is relatively low, the concentration turns out to be higher throughout the petroleum distillation process. Common nitrogen aromatic compounds in fossil fuels are shown in Figure 1.129 and physical properties of nitrogen aromatic compounds investigated in this research is shown in Table 2. Nitrogen aromatic compounds in fossil fuels fall into two classes. One is non-basic nitrogen compounds including indole and pyrrole due to the fact that the extra pair of electrons on N is contributed to the Ï€ electron cloud and is not available for interaction with acids. While the other class is basic nitrogen compounds such as pyridine, quinoline and their derivatives, in which the lone pair of electrons on N is available as an electron donor. Indole is one of the most common nitrogen compounds in fossil fuels, and it has been broadly studied. And we choose indole in our research due to the fact that indole is a weakly basic N-containing compound, which means it has a potential of selective adsorption against aromatic compounds and desorption is possible and reasonably convenient. Figure 3: Common nitrogen compounds existing in fossil fuels Table 2: Physical property of common nitrogen aromatic compounds existing in fossil fuels Compounds Formula Melting Point, ÃÅ'Ã…  C Density, g/cm3 Dipole moment, D Acidity,pKa Maximum diameter, ÃÅ'Ã…  A Indole C8H7N 52~54 1.17 2.11 16.2 6.9 Quinoline C9H7N -15 1.093 0 4.85 7.2 Isoquinoline C9H7N 26~28 1.099 0 5.14 7.2 1.4 Aromatic Compounds in Fossil Fuels Fossil fuels contain significant amount of hydrocarbons, most of them are aromatic compounds and polycyclic aromatic hydrocarbons (PAHs). In this research we choose naphthalene as representative aromatic compounds, and in order to investigate the adsorption mechanism we use fluorescence spectroscopy and UV-Vis diffuse reflectance spectroscopy to investigate electronic interactions upon adsorption onto MOFs. Naphthalene is the most simple and common aromatic compounds in PAHs. And naphthalene is commonly produced in petroleum refining and is then separated from the petroleum. Purification and separation of these aromatic rings is of interest in chemical industry. Naphthalene has a molecular length of 7.2 Ã… (largest diameter determined by ChemDraw 3D) and is non-polar. 1.5 Methods of Denitrogenation Microbial Denitrogenation Microbial process is an alternative pathway for denitrogenation. Microorganisms are known to consume natural organic compounds and convert them into carbons and energy, and they are capable of metabolizing certain molecules including nitrogen compounds from fossil fuels. The degradation of quinoline is well-characterized, and the transformation pathways are elucidated by M. Benedik et al29 (shown in Figure 1. 5). The degradation of isoquinoline is less understood but 1-oxo-1,2-dihydroisoquinoline is suggested as initial oxygenated product30. According to the finding of Claus, G, indole is readily degraded via catechol or transformed directly into tryptophan30, while carbazole is relatively more difficult to be degraded. One possible degradation pathway31 beginning with angular dioxygenation has been proposed by Ouchiyama, N., which finally enters TCA cycle after conversion to catechol or tryptophan32. Mechanisms for the degradation of other nitrogen compounds such as pyridine, quinol ine, acridine and their derivatives are reviewed in detail by J. Kaiser33. Recent research in microbial denitrogenation has revealed a promising future for application in selective removal of nitrogen- and sulfur-containing petroleum. However, as a major mechanism for the removal and metabolism of organic compounds from the environment, its’ characterization of the enzymes involving in the pathways is still under research29. And it has not been widely applied to the industry yet. Figure 4: Pathways for the transformation of quinoline Hydrodenigrogenation (HDN) Hydrodenitrogenation (HDN) is usually used to remove nitrogen compounds in fossil fuels during the refinery process, and Co-Mo catalyst is normally involved in the process. However, the HDS process is accomplished by reacting with hydrogen at high temperature and high pressure. It is energy-intensive, hazardous and costly. Thus, significant amount of researches have been done on HDN in order to reach a goal of being economic and environmentally friendly. Adsorptive Denitrogenation (ADN) Another promising way to selectively remove the nitrogen compounds in fossil fuels is adsorption on a porous material, Activated carbon34353637, Zeolites38, HCL-loaded silica-aluminas39, ion-exchange resins40, meso-silicas41,42, Ti-HMSs43, microporous carbon44, activated aluminas45, Ni-based adsorbents45, and NiMOs46 have been used for ADN. While recently the use of MOF adsorbents has gained significant interest in adsorption and separation of aromatic and heterocyclic compounds in liquid phase due to its’ high capacity, high selectivity, economic importance and most importantly energy saving 47. Moreover, MOFs can even be recycled and effectively reduce the cost. Adsorptive separation via â€Å"adsorptive denitrogenation (AND)† is preferred over industrial catalytic HDN10. Specifically, selective adsorption of N-heterocyclic compounds48 in presence of aromatic and aliphatic hydrocarbons in liquid phase49 is of interest, which is investigated in this research. 1.6 Activation of Open Metal Sites of Metal-Organic Frameworks Available CUS in MOFs is essential for the adsorption of Lewis basic compounds. Thus, to fully utilize the open metal sites in MOFs, activation is needed to evacuate the water molecules which are relatively weakly coordinated on these metals. Because MOFs are strongly adsorptive molecules, humidity can be crucial to the availability of open metal sites in MOFs. Specific treatment is necessary at certain temperature under vacuum in order to activate open metal sites. And protection of the sample against humidity is critical during experiments. Interestingly, it is discovered by K. Schlichte and his colleagues that upon activation the color of HKUST-1 would change from light cyan to dark navy50. This is confirmed by E. Borfecchia and his working group using UV-Vis, a red shift at LMCT edge and appearance of a shoulder in d-d band at around 600 nm in UV-Vis spectrum is observed and explained by the removal of water51. In addition to the activation of MOFs, partial reduction of MIL-100 (Fe) has been reported by H. Leclerc and his group52. Certain metal sites in MOF can be reduced, for example, Fe3+ in MIL-100 (Fe) can be reduced to Fe2+. According to their analysis of oxidation states via IR, outgassing at 423 K for 12 hour will give rise to a greater proportion of Fe2+ sites while minority of Fe3+ sites is reduced. However, outgassing at 523 K will result in that most Fe3+ sites are reduced. Fe3+ sites are more Lewis acidic sites than Fe2+, it is easier for Fe3+ to form coordination bond with nitrogen aromatics, which are good Lewis base. 1.7 Adsorption of Aromatic Compounds and Aromatic N-heterocyclic Compounds on mesoporous MOFs with CUS: MIL-100 (Fe) and F300 Although adsorption of small organic molecules on MOFs both in liquid phase and in vapor, such as toluene, benzene, xylene isomers2, etc., has been well studied in the recent years, to our knowledge the adsorption of fuse-ring aromatic hydrocarbons on MIL-100 in liquid phase has not been reported. M. Maes and his co-workers have reported adsorption of indole from heptane/toluene mixture solution on MIL-100 family9. Thus, mechanism of adsorption of aromatic compounds versus aromatic N-heterocyclic compounds on F300 has not been studied. According to many studies, the formation of complexes in liquid adsorption is usually assumed, but there is a lack of direct spectroscopic evidence. Adsorption of small aromatic ring compounds (benzene and p-xylene molecules) on MIL-101 has been published by K. Yang, et al2. Pore-size filling mechanism is discovered and discussed in this paper, indicating that pore-size and different substrate relates with molecular selectivity of organic compounds. Ho wever, the mechanism is still not understood. Fluorescence spectroscopy is a straightforward method for studying the adsorption mechanism between guest molecules and MOFs. Yet there are rarely papers studying characterization of adsorption of aromatic compounds in liquid or solid system by fluorescence spectroscopy. It is assumed based on fluorescence spectra that Lewis acid-base interaction promotes the adsorption of pyrene on Al2O3 from model fuel using octane as solvent53. While the fluorescence spectra was collected using a model sorbent aluminum chloride in methanol instead of actual Al2O3 in model fuel, spectroscopic characterization of adsorption complexes formed by MOFs and aromatic compounds or aromatic N-heterocyclic compounds by the fluorescence spectroscopy is still unknown to our knowledge. Another useful characterization method is near-UV/visible diffuse reflectance spectroscopy (DRS), which is excellent at detecting the variation or shift in electronic states on adsorption complexes forming by metal sites and guest molecules. The DRS was used to identify the interactions between aromatic amines and MOFs54 but it has not been used to explore the interactions between metal sites of MOFs and guest molecules as aromatic compounds or aromatic N-heterocyclic compounds. Thus, we aim to investigate the adsorption of large aromatic compounds on MOFs using two spectroscopic methods as fluorescence spectroscopy and near-UV/visible diffuse reflectance spectroscopy. 1.8 Adsorption of Aromatic Compounds and Aromatic N-heterocyclic compounds on microporous MOFs without CUS: MIL-53 and A100 M. Maes and his colleagues have studied the adsorption of indole and methyl-substituted indole present in model fuel (heptane/toluene at either 80 vol. %/20 vol. % or 20 vol. %/80 vol. % combination) at initial concentration of 0.15 M on thermally activated MIL-53 (Al)9. The amount of absorbed indole intensively dropped in model fuel with toluene, which indicates a possible competitive adsorption. While no data of adsorption capacity for indole and substituted indole on MIL-53 (Al) in n-alkane solvent was reported, not enough experimental evidence or computational evidence can be used to prove the mechanism of competitive adsorption. Similarly, adsorption of indole, pyridine, pyrrole and quinolone on thermally activated MIL-53 (Al) has been studied in another paper. In this paper n-octane was used as solvent, however, no data for adsorption capacity of indole on MIL-53 (Al) has been reported55. Ï€-Ï€ interactions is suggested to be the major force that introduce the adsorption of indole or quinolone onto activated MIL-53 (Al), but no experimental evidence was given55. At the present time, no direct spectroscopic characterization of chemical bonds between aromatic or hetero-aromatic adsorbate and MIL-53 has yet been reported. Furthermore, adsorption of naphthalene on MOFs has not been reported to our knowledge. To investigate the adsorption mechanisms through fluorescence spectroscopy, it is essential to know the origin of the fluorescence from MOF itselft. It was discussed in a review paper by M. Allendorf, C. Bauer, R. Bhakta et al.56, that there are five modes for generating fluorescence in MOFs: linker-based, framework metal ions (charge transfer between linker and metal), adsorb

The Color Purple Essay -- essays research papers fc

The Results of Celie’s Physical and Mental Abuse   Ã‚  Ã‚  Ã‚  Ã‚  In 1982 Alice Walker titled her Pulitzer Prize Winning novel, The Color Purple, which is symbolically meant to reflect radiance and majesty (Columbia). It is a story, entirely conveyed through letters, of one young black girl’s struggle to escape the brutal and degrading treatment by men, which had become a constant part of her life. Instead of focusing on race throughout the novel Walker accords â€Å"greater importance to power, the power to be, to concretize one’s self, as to mold others† (Dieke 102). This completely unbalanced power ultimately leaves Celie feeling alone and controlled, which affects her relationships with men and influences her relationship with women, mainly Shug Avery. The horrifying effects of rape and what Celie thought was incest so greatly scarred her for the rest of her life that she lost the ability to love, became confused about her sexuality, and subconsciously denied her right to an identity.   Ã‚  Ã‚  Ã‚  Ã‚  For a considerable amount of time Celie blindly accepted the fact that she would be treated like a slave in her own home. As a result, Celie demonstrated intense fear and a complete lack of love toward her husband. Because Mr. _____ had originally wanted to marry Celie’s older sister Nettie he felt that in settling for Celie he had the right to treat her as his property. Celie was completely aware of these arrangements â€Å"Mr. _____ marry me to take care of his children. I marry him cause my daddy made me. I don’t love Mr. _____ and he don’t love me† (Walker 57). As opposed to most marriages being based on trust, love, and commitment, their bond was based on authority, obedience, and service. Mr. _____ immediately brings Shug Avery into his home when he heard that she was sick so that Celie could take care of her along with his children from a previous marriage. After a short period of time Celie learns about their past and about Mr. _____’s current feelings for Shug. Celie’s blatant disregard to Mr. _____ sleeping with Shug again displays complete apathy toward her husband. Mr. _____’s aggressively dominant role does not denote the conventional husband/wife relationship it seems to more closely represent a master/slave relationship. Mr. _____’s constant oppressive presence causes Celie to live in continuous fear. Celie explains that M... ...novel Celie’s traumatic experiences have had a great impact on the entirety of her life. Once married she constantly lived in fear being incapable of love and unable to control her misguided sexual emotions.   Ã‚  Ã‚  Ã‚  Ã‚   Bibliography Bradley, David. â€Å"Novelist Alice Walker: Telling the Black Woman’s Story.† New York Times Magazine 8 Jan. 1984: 24-37. Dieke, Ikenna. Critical Essays on Alice Walker. Westport:   Ã‚  Ã‚  Ã‚  Ã‚  Greenwood Press,1999. Gates, Henry Louis Jr. and K.A. Appiah. Alice Walker   Ã‚  Ã‚  Ã‚  Ã‚  Critical Perspectives Past and Present. NewYork:   Ã‚  Ã‚  Ã‚  Ã‚  Amistad Press Inc, 1993. http://www.Womenshistroy.about.com â€Å"Race and Domesticity in The Color Purple† African American   Ã‚  Ã‚  Ã‚  Ã‚  Review 29 #1 Spring 1995:67-82. The Columbia Encyclopedia, Sixth Edition Copyright 2001   Ã‚  Ã‚  Ã‚  Ã‚  Columbia University Press. Walker, Alice. The Color Purple. Orlando: Harcourt Brace   Ã‚  Ã‚  Ã‚  Ã‚  Jovanovich Publishers 1982. Walsh, Margaret. â€Å"The Enchanted World of the Color Purple.†   Ã‚  Ã‚  Ã‚  Ã‚  Southern Quarterly 25 (1987): 89-101.